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4 de jul. de 2008 · This paper explores the design and control of the maximum-boiling azeotropic acetone/chloroform distillation system. The normal boiling points of the two pure components are 329.4 and 334.3 K, while the azeotropic boils at 337.6 K at 1 atm with a composition of 34.09 mol % acetone.
chloroform: 61.1: 53.5: 87.4 1.342 carbon tetrachloride: 76.8: 55.7: 79.4 1.322 ethyl bromide: 38.4: 35.0: 95.5: n-propyl chloride: 46.6: 40.5: 90.5: isopropyl chloride: 36.4: 33.4: 94: n-propyl bromide: 71.0: 54.5: 79: isopropyl bromide: 59.8: 48.6: 85.0: isopropyl iodide: 89.4: 61.0: 62: trichloroethylene: 87.2: 60.2: 64 ...
Thermodynamic Studies of the System: Acetone + Chloroform. Charles R. Mueller. and. Edward R. Kearns. Cite this: J. Phys. Chem. 1958, 62, 11, 1441–1445. Publication Date: November 1, 1958. https://doi.org/10.1021/j150569a023. © American Chemical Society. Request reuse permissions. Article Views. 483. Altmetric. 3. Citations. 48.
15 de ago. de 2019 · The NRTL-SAC model could not appropriately predict the maximum azeotrope temperature systems, in particular for acetone-chloroform, chloroform-methyl acetate, and chloroform-diethyl amine systems. For these systems, the NRTL-SAC model gave a minimum azeotrope temperature.
Chloroform may also be produced on a small scale via the haloform reaction between acetone and sodium hypochlorite: 3 NaOCl + (CH 3) 2 CO → CHCl 3 + 2 NaOH + CH 3 COONa Deuterochloroform
1 de ene. de 1980 · The physical parameters of chloroform: (d = 1.4799 g cm~, 45 = 1.4421) and of acetone: (d = 0.7862 g cm3, 45 = 1.3 560) are in satisfactory agreement with other investigations, especially for chloroform. There is much disagreement in the literature concerning the density of acetone.
6 de nov. de 2008 · Chloroform, a C-H hydrogen bond donor, can form weak hydrogen bonded complexes with acetone and with dimethylsulfoxide (DMSO). When chloroform is dissolved in a mixed solvent consisting of acetone and DMSO, both types of hydrogen bonded complexes exist.
