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  1. Co (H 2 O) 62+aq + 4 Cl -aq (+ heat) → CoCl 42-aq + 3 H 2 O l. The blue form is anhydrous and tetrahedral coordinated, the pink form is hydrated and is octahedral coordinated. ΔH = ~42-54kJ/mol. Conc. HCl is not only a source of Cl - but also has a dehydrating effect. This demonstration projects well on an overhead, with a petri dish.

  2. Watch as the equilibrium between two different coloured cobalt species is disturbed, accompanied by a colour change predicted by Le Chatelier’s principle. The two different coloured Co (II) complex ions, [Co (H 2 O) 6] 2+ and [CoCl 4] 2-, exist together in equilibrium in solution in the presence of chloride ions:

  3. Cobalt Complex Equilibrium. Temperature and Concentration Effects: Purpose. To demonstrate the shift in equilibrium caused by a change of temperature and a change in concentration. Materials. 0.4 M CoCl2 (5.2g/100 mL H2O) 0.2 M CoCl2 (2.6g/100 mL H2O) 0.1 M AgNO3 (1.7g/100 mL H2O) concentrated. HCl 250 mL beaker.

  4. We begin by dissolving the Cobalt Chloride in water, forming the pink hydrous form. The system’s equilibrium is then stressed by adding substances that affect concentrations or other parameters. 2- 2 [CoCl 4] (aq) 6H 2O (l)[Co(H 2O) 6] (aq) 4Cl (aq) + ++! (blue) (pink)

  5. 27 de ene. de 2023 · Equilibria of complexes in the aqueous cobalt (II)–N- (2-hydroxybenzyl)phenylalanine system and their biological activity compared to analogous Schiff base structures - PMC. Journal List. Comput Struct Biotechnol J. v.21; 2023. PMC9939546. As a library, NLM provides access to scientific literature.

  6. 3 de mar. de 2011 · Abstract. By adding a large quantity of Cl − to an aqueous solution of CoCl 2 ·6H 2 O, a mixture containing a red octahedral cobalt complex and a blue tetrahedral complex is produced. When the solution temperature is modified, the equilibrium constant, Keq, of the complexation reaction is shifted and the proportion of the two ...