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How do you predict which ligands are strong sigma donors in metal complexes? I am learning about the trans effect in my inorganic chemistry class on the rate and stereo chemistry of ligand substitution reactions. I understand that a strong sigma donor ligand will lead to a weaker metal ligand bond trans to the strong sigma donor.
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Sigma bond is the strongest covalent bond, owing to the direct overlapping of the contributing orbitals. The bonding electrons are usually referred to as sigma electrons. Generally, all single bonds are sigma bonds. They can be formed via the following combinations of atomic orbitals. 1. s-s Overlapping.
Hace 6 días · Given a Hilbert space H, the sigma-strong operator topology is the topology on the algebra L(H) of bounded operators from H to itself defined as follows: A sequence S_i of operators in L(H) converges to an operator S in L(H) sigma-strongly if and only if S_iT->ST for all compact operators T:H->H.
